England produced another top class bowling effort after winning the toss with Chris Woakes taking four wickets and Ollie Robinson taking three.
Robinson dismissed Virat Kohli for the third time in the series with the India skipper departing after a well made fifty. India reached 122 for six at tea.
India struggled against the moving ball in the morning session, struggling to 54 for three at lunch.
Joe Root put India in to bat amid overcast conditions. Coming back from injury, Woakes made instant impact by having Rohit Sharma (11) caught behind in his first over.
Robinson then trapped K L Rahul (17) with a ball that nipped backed in.
Cheteshwar Pujara followed an outswinger from James Anderson only to edge it to the wicketkeeper to leave India reeling at 39 for three.
Jadeja came ahead of Rahane and Pant.
Brief scores: India 191 all out in 61.3 overs (Virat Kohli 50, Shardul Thakur 57; James Anderson 1/41, Ollie Robinson 3/38, Chris Woakes 4/55, Craig Overton 1/49).
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